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丁酮BUTANONE物质安全资料表 MSDS

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2024年4月23日发(作者:力柏)

SAFETY DATA SHEET

WL-200 WASH

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

PRODUCT NAME

PRODUCT NO.

WL-200 WASH

WL-200

SUPPLIER

2 COMPOSITION/INFORMATION ON INGREDIENTS

Name

BUTANONE

EC No.

201-159-0

CAS-No.

78-93-3

ContentClassification

90-100%F;R11 Xi;R36 R66 R67

The Full Text for all R-Phrases are Displayed in Section 16

3 HAZARDS IDENTIFICATION

Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and

dizziness.

CLASSIFICATIONXi;R36. F;R11. R66, R67.

4 FIRST-AID MEASURES

GENERAL INFORMATION

NOTE! Keep affected person away from heat, sparks and flames! Keep the affected person warm and at rest. Get prompt medical

attention.

INHALATION

Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and

at rest. Get prompt medical attention.

INGESTION

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Promptly get affected person to drink large volumes of water to

dilute the swallowed chemical. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn''t

enter the lungs. Get medical attention.

SKIN CONTACT

Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any

discomfort continues.

EYE CONTACT

Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA

Use: Alcohol resistant foam. Powder. Dry chemicals, sand, dolomite etc.

SPECIAL FIRE FIGHTING PROCEDURES

Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities.

Use water to keep fire exposed containers cool and disperse vapours. Move container from fire area if it can be done without risk.

UNUSUAL FIRE & EXPLOSION HAZARDS

Vapours are heavier than air and may spread near ground to sources of ignition. May explode when heated or when exposed to flames or

sparks. May form explosive or toxic mixtures with air.

SPECIFIC HAZARDS

Fire creates: Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2).

6 ACCIDENTAL RELEASE MEASURES

1/4

WL-200 WASH

SPILL CLEAN UP METHODS

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or

liquid contact protection. Runoff or release to sewer, waterway or ground is forbidden. Small Spillages Collect with absorbent,

non-combustible material into suitable containers. Large Spillages Absorb in vermiculite, dry sand or earth and place into containers.

Inform Authorities if large amounts are involved.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use

approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static

electricity and formation of sparks must be prevented.

STORAGE PRECAUTIONS

Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a cool, dry

well-ventilated place. Keep in original container.

STORAGE CLASS

Flammable liquid storage.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name

BUTANONE

INGREDIENT COMMENTS

WEL = Workplace Exposure Limits

PROTECTIVE EQUIPMENT

Std

WEL

LT - ppm

200 ppm(Sk)

LT - mg/m3

600 mg/m3(Sk)

ST - ppm

300 ppm(Sk)

ST - mg/m3

899 mg/m3(Sk)

PROCESS CONDITIONS

Provide eyewash station.

ENGINEERING MEASURES

Well-ventilated area.

RESPIRATORY EQUIPMENT

No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended Workplace

Exposure Limit.

HAND PROTECTION

Use protective gloves made of: Polyvinyl alcohol (PVA). P.T.F.E (Teflon). Nitrile.

EYE PROTECTION

Wear splash-proof eye goggles to prevent any possibility of eye contact.

OTHER PROTECTION

Wear appropriate clothing to prevent any possibility of skin contact.

HYGIENE MEASURES

DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes wet or contaminated. Wash promptly if skin becomes wet

or contaminated. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. Wash at

the end of each work shift and before eating, smoking and using the toilet.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

COLOUR

ODOUR

SOLUBILITY

Liquid

Clear

Ketonic.

Soluble in Organic solvents Slightly soluble in water.

MOL. WEIGHT

MELTING POINT (°C)

VAPOUR DENSITY (air=1)

VOLATILE BY VOL. (%)

FLASH POINT (°C)

FLAMMABILITY LIMIT - UPPER(%)

72.1

- 86.5

2.4

100

-4 CC (Closed cup).

11.5

BOILING POINT (°C)

RELATIVE DENSITY

VAPOUR PRESSURE

VISCOSITY

FLAMMABILITY LIMIT - LOWER(%)

~ 75 - 85 760 mm Hg

0.80 @ 20 °c

8.9 kPa @ 20 °c

1.00 cps @ 20 °c

1.8

10 STABILITY AND REACTIVITY

STABILITY

Stable under normal temperature conditions.

2/4

WL-200 WASH

CONDITIONS TO AVOID

Avoid contact with strong oxidisers.

HAZARDOUS DECOMPOSITION PRODUCTS

Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

11 TOXICOLOGICAL INFORMATION

HEALTH WARNINGS

EYE CONTACT. Irritant of eyes and mucous membranes. INGESTION. Narcotic effect. INHALATION. CNS depressant. Prolonged

inhalation of high concentrations may damage respiratory system. SKIN CONTACT. Acts as a defatting agent on skin. May cause

cracking of skin, and eczema.

ROUTE OF ENTRY

Ingestion. Skin absorption. Inhalation.

MEDICAL SYMPTOMS

NERVOUS SYSTEM. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irritability, headache,

nausea).

12 ECOLOGICAL INFORMATION

ECOTOXICITY

Little danger to the environment.

LC 50, 96 Hrs, FISH mg/l

EC 50, 48 Hrs, DAPHNIA, mg/l

IC 50, 72 Hrs, ALGAE, mg/l

DEGRADABILITY

Will degrade.

ACUTE FISH TOXICITY

May be harmful to aquatic organisms in large quantities.

>100

>100

>100

13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS

Contact specialist disposal companies. Do not allow runoff to sewer, waterway or ground. Empty containers must not be burned because

of explosion hazard. Absorb in vermiculite or dry sand, dispose in licensed special waste. Dispose of waste and residues in accordance

with local authority requirements.

14 TRANSPORT INFORMATION

PROPER SHIPPING NAMEETHYL METHYL KETONE

UN NO. ROAD

ADR CLASS

ADR LABEL NO.

RID CLASS NO.

IMDG CLASS

EMS

MARINE POLLUTANT

ICAO CLASS

1193

Class 3: Flammable liquids.

3

3

3

F-E, S-D

No.

3

ADR CLASS NO.

ADR PACK GROUP

HAZCHEM CODE

UN NO. SEA

IMDG PACK GR.

MFAG

UN NO. AIR

AIR PACK GR.

3

II

2(Y)E

1193

II

See Guide

1193

II

15 REGULATORY INFORMATION

LABELLING

IrritantHighly Flammable

RISK PHRASES

R11Highly flammable.

3/4

WL-200 WASH

R36

R66

R67

SAFETY PHRASES

S16

S33

S7/9

S24/25

S60

STATUTORY INSTRUMENTS

Chemicals (Hazard Information and Packaging) Regulations.

Control of Substances Hazardous to Health.

APPROVED CODE OF PRACTICE

Safety Data Sheets for Substances and Preparations.

Classification and Labelling of Substances and Preparations.

Chemical Industries Association - Guidance on the compilation of safety data sheets.

GUIDANCE NOTES

Workplace Exposure Limits EH40.

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharges.

Keep container tightly closed and in a well-ventilated place.

Avoid contact with skin and eyes.

This material and its container must be disposed of as hazardous waste.

Irritating to eyes.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

16 OTHER INFORMATION

INFORMATION SOURCES

Dangerous Properties of Industrial Materials Report, . Croner´s: Emergency Spillage Guide. Croner´s: Substances Hazardous

to Health. Croner´s: Emergency First Aid Guide. Croner´s: Dangerous Substances.

REVISION DATE

REV. NO./REPL. SDS GENERATED 5

RISK PHRASES IN FULL

R11Highly flammable.

Irritating to eyes.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

R36

R66

R67

4/4

2024年4月23日发(作者:力柏)

SAFETY DATA SHEET

WL-200 WASH

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

PRODUCT NAME

PRODUCT NO.

WL-200 WASH

WL-200

SUPPLIER

2 COMPOSITION/INFORMATION ON INGREDIENTS

Name

BUTANONE

EC No.

201-159-0

CAS-No.

78-93-3

ContentClassification

90-100%F;R11 Xi;R36 R66 R67

The Full Text for all R-Phrases are Displayed in Section 16

3 HAZARDS IDENTIFICATION

Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and

dizziness.

CLASSIFICATIONXi;R36. F;R11. R66, R67.

4 FIRST-AID MEASURES

GENERAL INFORMATION

NOTE! Keep affected person away from heat, sparks and flames! Keep the affected person warm and at rest. Get prompt medical

attention.

INHALATION

Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and

at rest. Get prompt medical attention.

INGESTION

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Promptly get affected person to drink large volumes of water to

dilute the swallowed chemical. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn''t

enter the lungs. Get medical attention.

SKIN CONTACT

Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any

discomfort continues.

EYE CONTACT

Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA

Use: Alcohol resistant foam. Powder. Dry chemicals, sand, dolomite etc.

SPECIAL FIRE FIGHTING PROCEDURES

Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities.

Use water to keep fire exposed containers cool and disperse vapours. Move container from fire area if it can be done without risk.

UNUSUAL FIRE & EXPLOSION HAZARDS

Vapours are heavier than air and may spread near ground to sources of ignition. May explode when heated or when exposed to flames or

sparks. May form explosive or toxic mixtures with air.

SPECIFIC HAZARDS

Fire creates: Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2).

6 ACCIDENTAL RELEASE MEASURES

1/4

WL-200 WASH

SPILL CLEAN UP METHODS

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or

liquid contact protection. Runoff or release to sewer, waterway or ground is forbidden. Small Spillages Collect with absorbent,

non-combustible material into suitable containers. Large Spillages Absorb in vermiculite, dry sand or earth and place into containers.

Inform Authorities if large amounts are involved.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use

approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static

electricity and formation of sparks must be prevented.

STORAGE PRECAUTIONS

Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a cool, dry

well-ventilated place. Keep in original container.

STORAGE CLASS

Flammable liquid storage.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name

BUTANONE

INGREDIENT COMMENTS

WEL = Workplace Exposure Limits

PROTECTIVE EQUIPMENT

Std

WEL

LT - ppm

200 ppm(Sk)

LT - mg/m3

600 mg/m3(Sk)

ST - ppm

300 ppm(Sk)

ST - mg/m3

899 mg/m3(Sk)

PROCESS CONDITIONS

Provide eyewash station.

ENGINEERING MEASURES

Well-ventilated area.

RESPIRATORY EQUIPMENT

No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended Workplace

Exposure Limit.

HAND PROTECTION

Use protective gloves made of: Polyvinyl alcohol (PVA). P.T.F.E (Teflon). Nitrile.

EYE PROTECTION

Wear splash-proof eye goggles to prevent any possibility of eye contact.

OTHER PROTECTION

Wear appropriate clothing to prevent any possibility of skin contact.

HYGIENE MEASURES

DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes wet or contaminated. Wash promptly if skin becomes wet

or contaminated. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. Wash at

the end of each work shift and before eating, smoking and using the toilet.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

COLOUR

ODOUR

SOLUBILITY

Liquid

Clear

Ketonic.

Soluble in Organic solvents Slightly soluble in water.

MOL. WEIGHT

MELTING POINT (°C)

VAPOUR DENSITY (air=1)

VOLATILE BY VOL. (%)

FLASH POINT (°C)

FLAMMABILITY LIMIT - UPPER(%)

72.1

- 86.5

2.4

100

-4 CC (Closed cup).

11.5

BOILING POINT (°C)

RELATIVE DENSITY

VAPOUR PRESSURE

VISCOSITY

FLAMMABILITY LIMIT - LOWER(%)

~ 75 - 85 760 mm Hg

0.80 @ 20 °c

8.9 kPa @ 20 °c

1.00 cps @ 20 °c

1.8

10 STABILITY AND REACTIVITY

STABILITY

Stable under normal temperature conditions.

2/4

WL-200 WASH

CONDITIONS TO AVOID

Avoid contact with strong oxidisers.

HAZARDOUS DECOMPOSITION PRODUCTS

Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

11 TOXICOLOGICAL INFORMATION

HEALTH WARNINGS

EYE CONTACT. Irritant of eyes and mucous membranes. INGESTION. Narcotic effect. INHALATION. CNS depressant. Prolonged

inhalation of high concentrations may damage respiratory system. SKIN CONTACT. Acts as a defatting agent on skin. May cause

cracking of skin, and eczema.

ROUTE OF ENTRY

Ingestion. Skin absorption. Inhalation.

MEDICAL SYMPTOMS

NERVOUS SYSTEM. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irritability, headache,

nausea).

12 ECOLOGICAL INFORMATION

ECOTOXICITY

Little danger to the environment.

LC 50, 96 Hrs, FISH mg/l

EC 50, 48 Hrs, DAPHNIA, mg/l

IC 50, 72 Hrs, ALGAE, mg/l

DEGRADABILITY

Will degrade.

ACUTE FISH TOXICITY

May be harmful to aquatic organisms in large quantities.

>100

>100

>100

13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS

Contact specialist disposal companies. Do not allow runoff to sewer, waterway or ground. Empty containers must not be burned because

of explosion hazard. Absorb in vermiculite or dry sand, dispose in licensed special waste. Dispose of waste and residues in accordance

with local authority requirements.

14 TRANSPORT INFORMATION

PROPER SHIPPING NAMEETHYL METHYL KETONE

UN NO. ROAD

ADR CLASS

ADR LABEL NO.

RID CLASS NO.

IMDG CLASS

EMS

MARINE POLLUTANT

ICAO CLASS

1193

Class 3: Flammable liquids.

3

3

3

F-E, S-D

No.

3

ADR CLASS NO.

ADR PACK GROUP

HAZCHEM CODE

UN NO. SEA

IMDG PACK GR.

MFAG

UN NO. AIR

AIR PACK GR.

3

II

2(Y)E

1193

II

See Guide

1193

II

15 REGULATORY INFORMATION

LABELLING

IrritantHighly Flammable

RISK PHRASES

R11Highly flammable.

3/4

WL-200 WASH

R36

R66

R67

SAFETY PHRASES

S16

S33

S7/9

S24/25

S60

STATUTORY INSTRUMENTS

Chemicals (Hazard Information and Packaging) Regulations.

Control of Substances Hazardous to Health.

APPROVED CODE OF PRACTICE

Safety Data Sheets for Substances and Preparations.

Classification and Labelling of Substances and Preparations.

Chemical Industries Association - Guidance on the compilation of safety data sheets.

GUIDANCE NOTES

Workplace Exposure Limits EH40.

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharges.

Keep container tightly closed and in a well-ventilated place.

Avoid contact with skin and eyes.

This material and its container must be disposed of as hazardous waste.

Irritating to eyes.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

16 OTHER INFORMATION

INFORMATION SOURCES

Dangerous Properties of Industrial Materials Report, . Croner´s: Emergency Spillage Guide. Croner´s: Substances Hazardous

to Health. Croner´s: Emergency First Aid Guide. Croner´s: Dangerous Substances.

REVISION DATE

REV. NO./REPL. SDS GENERATED 5

RISK PHRASES IN FULL

R11Highly flammable.

Irritating to eyes.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

R36

R66

R67

4/4

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